4-[(4-Methylanilino)methyl]benzonitrile
نویسنده
چکیده
The asymmetric unit of the title compound, C(15)H(14)N(2), contains two mol-ecules. The amine NH group connects two aromatic systems with similar C-N-C bond angles of 120.96 (16) and 119.75 (16)° for each independent mol-ecule. In contrast, the dihedral angles between the benzene rings are significantly different for the two independent mol-ecules, viz. 69.1 (2) and 79.9 (2)°.
منابع مشابه
4-[(2H-Tetrazol-2-yl)methyl]benzonitrile
The title compound, C(9)H(7)N(5), was synthesized by reaction of 4-(bromomethyl)benzonitrile and 2H-tetrazole in the presence of KOH. The relative orientation of the planar tetra-zole ring and the methyl-benzonitrile moiety is (-)-anti-clinal. The crystal packing is dominated by van der Waals inter-actions.
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The title compound, C(22)H(31)NO, has been synthesized from 4-bromo-methyl-2,6-di-tert-butyl-phenol and N-methyl-aniline. There are two independent mol-ecules in the asymmetric unit. The aniline ring in each of the independent mol-ecules was found to be disordered, with site occupation factors 0.621 (10)/0.379 (10) and 0.605 (10)/0.395 (10).
متن کامل4-[(1H-Benzotriazol-1-yl)methyl]benzonitrile
In the mol-ecule of the title compound, C(14)H(10)N(4), which was prepared by reaction of benzotriazole with 4-(bromo-meth-yl)benzonitrile in alkaline solution, the dihedral angle between the benzotriazole and benzene ring systems is 69.03 (6)°.
متن کامل4-[(2-Hydroxynaphthalen-1-yl)(morpholin-4-yl)methyl]benzonitrile
The title compound, C(22)H(20)N(2)O(2), was synthesized via a multicomponent reaction using naphthalen-2-ol, morpholine and 4-formyl-benzonitrile. The dihedral angle between the naphthalene ring system and the benzene ring is 81.25 (10)°. The morpholine ring adopts a chair conformation. The mol-ecular conformation is stabilized by intra-molecular O-H⋯N and C-H⋯O hydrogen bonds. In the crystal, ...
متن کامل4-[(2-Hydroxy-1-naphthyl)(piperidin-1-yl)methyl]benzonitrile
In the title compound, C(23)H(22)N(2)O, obtained from the condensation reaction of 4-formyl-benzonitrile, 2-naphthol and piperidine, the dihedral angle between the naphthalene ring system and the benzene ring is 75.31 (4)°. The piperidine ring adopts a chair conformation. The crystal structure is stabilized by inter-molecular C-H⋯N hydrogen bonds, which link the mol-ecules into centrosymmetric ...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011